Ammonia

Beyond Fertilizer: The Future of Low-Emission Ammonia

In this episode of Innovate and React, I met with Kevin Rouwenhorst, the technology manager at the Ammonia Energy Association, to discuss the future of sustainable ammonia synthesis. We explore his journey into the clean molecule space, which ultimately led him to write a comprehensive book on low-emission ammonia technologies. Kevin clarifies a common misconception about the traditional Haber-Bosch process, explaining that over 90% of its CO2 emissions actually stem from hydrogen production, such as steam methane reforming or coal gasification, rather than the ammonia synthesis loop itself.
The conversation dives deep into the challenges of decarbonizing this massive industry, focusing on the high costs of scaling green electrolytic hydrogen and the complexities of retrofitting existing plants for carbon capture. We discuss the engineering hurdles of designing flexible ammonia plants that can adapt to the variable loads of renewable energy sources. Beyond its traditional use in fertilizers, we explore exciting emerging use cases for low-emission ammonia, including its adoption as a zero-carbon maritime fuel, and its potential for power generation, such as co-firing in thermal plants and fueling combined cycle gas turbines. The episode concludes with a look at safety standards, the geopolitical implications of localizing energy production, and the fascinating history behind the Haber-Bosch process and Alwin Mittasch’s catalyst discovery.

Why Reversing the Haber-Bosch Process Requires a New Catalyst

In this episode of Innovate and React, I met with Malte Behrens, a professor of inorganic solid-state chemistry at the University of Kiel, to discuss ammonia as a vital carrier for the hydrogen economy. We explore the challenges of transporting pure hydrogen and how converting it into ammonia offers a more practical, carbon-free solution due to its ease of liquefaction and higher volumetric energy density. Malte shares his journey from solid-state chemistry to heterogeneous catalysis. The conversation dives deep into the necessity of discovering effective and scalable catalysts to decompose, or “crack” ammonia back into hydrogen gas for energy use and nitrogen.
The discussion highlights the limitations of using traditional iron catalysts, as well as the economic barriers of using highly active but expensive ruthenium. To solve this, Malte’s research focuses on alloying iron with cobalt to prevent bulk nitridation, effectively finding the optimal balance of binding energy on the Sabatier volcano curve. The episode concludes with a look at the future of green ammonia, emphasizing the need for renewable energy-driven electrolysis to power a sustainable global energy trade.

One chemical reaction to feed them all: The synthesis of ammonia

In this episode of Innovate and React, I delve into the groundbreaking discovery of the Haber-Bosch process, which revolutionized agriculture and the chemical industry by synthesizing ammonia from atmospheric nitrogen and hydrogen. Starting with a historical perspective from the 19th, the episode explores the pivotal contributions of Fritz Haber and Carl Bosch to the invention of the Haber-Bosch process. It covers the scientific challenges, innovations, and controversies surrounding Haber’s research, and how Bosch made the reaction viable for industrial scale. The episode also discusses the modern impact and future applications of ammonia in renewable energy systems.

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